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8 Mar 2014 Imagine the reaction below is part of the free radical substitution mechanism that occurs when chlorine and methane react at room temperature and pressureIn organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction Halogenation often does not stop at monosubstitution. chlorination, but also highly exothermic and care must be taken to prevent an explosion or a runaway reaction. . Create a book · Download as PDF · Printable version In organic chemistry, a radical-substitution reaction is a substitution reaction involving free Create a book · Download as PDF · Printable version Imagine the reaction below is part of the free radical substitution mechanism that occurs when chlorine and methane react at room temperature and pressure Ab initio calculations predict that homolytic substitution reactions involving silyl, data is made available by participants in Crossref's Cited-by Linking service. Radical Substitution Mechanism. Unlike the large majority of reactions that you will see in your organic chemistry course, radical mechanisms require that 8 Jun 2016